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81.
Xiaoxiao Xu Prof. Caihong Fang Ting Bi Zhiqing Cui Guili Zhao Xiaomin Jiang Jinwu Hu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(47):10787-10794
Plasmonic nanostructures with large absorption areas under resonant excitation have been utilized extensively in photon-assisted applications. In this work, dodecahedral Au nanobowls were first prepared by an easy and template-free method only through the introduction of H2PtCl6 and I− during the growth procedure. The Au nanobowls show electron-field enhancement due to the high curvature of the bowl edge, the open region, and dodecahedral morphology. Au/Pt nanobowls, which couple plasmonic Au and catalytic Pt, were then constructed as plasmonic electrocatalysts for methanol oxidation. The mass activity reached 497.6 mA mg−1 under visible-light illumination, which is 1.9 times that measured in the dark. Simultaneously, the electrocatalytic stability is also greatly improved under light excitation. The enhanced properties of the plasmonic Au/Pt electrocatalysts are ascribed to the synergistic effect of the plasmon-enhanced photothermal and hot-carrier effects on the basis of experimental investigations. This work thus offers an effective methodology to construct efficient plasmonic electrocatalysts for fuel cells. 相似文献
82.
Xinxin Lin Prof. Zheng Fang Cuilian Zeng Chenlong Zhu Xinyan Pang Chengkou Liu Wei He Jindian Duan Ning Qin Prof. Kai Guo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(60):13738-13742
A non-oxidant and metal-free strategy for synthesizing iso-coumarin by using a continuous electrochemical microreactor to initiate an oxidative cyclization reaction of o-(1-alkynyl) benzoate and radicals. This efficient and clean continuous electrosynthesis method not only avoids the complicated gas protection operation and production of by-products in the batch processes, but also help to overcome the difficulty that batch metal catalysis and electrocatalysis are difficult to scale up, and has the potential for pilot-scale experiment. 相似文献
83.
Weimin Shi Jingjie Zhang Fengqian Zhao Wei Wei Fang Liang Yin Zhang Prof. Dr. Shaolin Zhou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(65):14823-14827
In this work, a mild and transition-metal-free approach for the nucleophilic aromatic substitution (SNAr) of unactivated fluoroarenes with primary aliphatic amines to form aromatic amines is reported. This reaction is facilitated by the formation of cationic fluoroarene radical intermediates in the presence of an acridinium-based organic photocatalyst under blue-light irradiation. Various electron-rich and electron-neutral fluoroarenes are competent electrophiles for this transformation. A wide range of primary aliphatic amines, including amino acid esters, dipeptides, and linear and branched amines are suitable nucleophiles. The synthetic utility of this protocol is demonstrated by the late-stage functionalization of several complex drug molecules. 相似文献
84.
Chenxia Kang Dr. Ju Fang Likang Fu Shuxian Li Prof. Qiming Liu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(69):16392-16401
A 3D hierarchical carbon cloth/nitrogen-doped carbon nanowires/Ni@MnO2 (CC/N-CNWs/Ni@MnO2) nanocomposite electrode was rationally designed and prepared by electrodeposition. The N-CNWs derived from polypyrrole (PPy) nanowires on the carbon cloth have an open framework structure, which greatly increases the contact area between the electrode and electrolyte and provides short diffusion paths. The incorporation of the Ni layer between the N-CNWs and MnO2 is beneficial for significantly enhancing the electrical conductivity and boosting fast charge transfer as well as improving the charge-collection capacity. Thus, the as-prepared 3D hierarchical CC/N-CNWs/Ni@MnO2 electrode exhibits a higher specific capacitance of 571.4 F g−1 compared with those of CC/N-CNWs@MnO2 (311 F g−1), CC/Ni@MnO2 (196.6 F g−1), and CC@MnO2 (186.1 F g−1) at 1 A g−1 and remarkable rate capability (367.5 F g−1 at 10 A g−1). Moreover, asymmetric supercapacitors constructed with CC/N-CNWs/Ni@MnO2 as cathode material and activated carbon as anode material deliver an impressive energy density of 36.4 W h kg−1 at a power density of 900 W kg−1 and a good cycling life (72.8 % capacitance retention after 3500 cycles). This study paves a low-cost and simple way to design a hierarchical nanocomposite electrode with large surface area and superior electrical conductivity, which has wide application prospects in high-performance supercapacitors. 相似文献
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87.
通过介绍混合教学模式在有机化学实验课程教学中的设计、实施情况及效果评价与反馈等内容,与大家分享混合教学模式在有机化学实验课程教学中的应用经验与思考。 相似文献
88.
高等教育要适应世界潮流和时代变化,本科教育须进一步提高实践教学的比重,加强理论教学与实践教学相结合,完善协同育人机制。结合学科发展和企业发展需求,中山大学化学学院与金发科技股份有限公司(简称金发科技)共同建设大学生实践教学基地。本文以中山大学-金发科技本科实践教学基地为例,探讨大学生校外实践基地建设过程中遇到的问题以及实践基地的建设内容与成果体会。 相似文献
89.
Characteristics of uranium sorption on illite in a ternary system: effect of phosphate on adsorption
Liao Rong Shi Zeming Chen Yuejiao Zhang Junji Wang Xinyu Hou Yun Zhang Kailiang 《Journal of Radioanalytical and Nuclear Chemistry》2020,324(1):159-167
Journal of Radioanalytical and Nuclear Chemistry - Na, Mg, Al and Cl in Roman glasses and pottery were analyzed by PIGE with 2.5 MeV protons and 2.0 MeV deuteron activation... 相似文献
90.
肝损伤是影响公众健康的重大问题之一, 已经引起了人们越来越多的关注. 而过表达的过氧化亚硝酸盐(ONOO?)在肝损伤等疾病的发病机制中起着重要作用, 被认为是一种与早期肝损伤密切相关的生物活性分子. 因此, 为了探究ONOO?在肝损伤过程中的作用, 开发可以实现肝损伤过程中ONOO?高选择性和实时检测的分析方法具有重要意义. 本文报道了一种具有大斯托克斯位移的远红光至近红外(FR-NIR)ONOO?荧光探针. 由于该探针具有大的斯托克斯位移, 可以有效消除光谱重叠和自吸收的干扰, 从而显著提高成像的信噪比. 此外, 该探针对ONOO?具有高的灵敏度(检出限为25.8 nmol/L)和良好的选择性, 被成功用于药物诱导肝损伤过程中ONOO?信号的成像检测. 相似文献